Actions

Download Analytics Citations

Export to: EndNote  |  Zotero  |  Mendeley

Collections

This file is not currently in any collections.

Structure of the polyvinylpyrrolidone-hydrogen peroxide complex [dataset] Open Access

The structure of the polyvinylpyrrolidone-hydrogen peroxide complex can be understood by reference to the co-crystal structure of hydrogen peroxide with a two-monomer unit model compound, bisVP·2H2O2. Crystallization at low peroxide concentration gives mixed hydrates in which water selectively substitutes to varying degree into one of the two independent hydrogen peroxide binding sites. The hydrogen bonding structures found in the co-crystals in conjunction with solid state 13C NMR and IR spectroscopic data, and DFT calculations on four- and six-monomer unit sections of PVP models gives considerable insight into the structure and properties of this commercially important complex.

Descriptions

Resource type

Dataset

Contributors

Contact person: Steed, Jonathan ¹
Data curator: Steed, Jonathan ¹
Creator: Chambers, Luke ¹
Data collector: Chambers, Luke ¹
Creator: Fox, Mark ¹
Data collector: Fox, Mark ¹

¹ Durham University, UK

Funder

Engineering and Physical Sciences Research Council
Ashland

Research methods

IR spectroscopy Solid State NMR spectroscopy DFT calculations

Other description

Keyword

Peroxydone
PVP

Subject

Location

Language

Cited in

Identifier

ark:/32150/r2k06987519
doi:10.15128/r2k06987519

Rights

Creative Commons Attribution 4.0 International (CC BY)

Publisher

Durham University

Date Created

6/10/21

File Details

Depositor

J.W. Steed

Date Uploaded

6 October 2021, 17:10:24

Date Modified

8 October 2021, 10:10:52

Audit Status

Audits have not yet been run on this file.

Characterization

File format: zip (ZIP Format)

Mime type: application/zip

File size: 628528

Last modified: 2021:10:08 10:09:58+01:00

Filename: Peroxydone_Data.zip

Original checksum: 8c1bda362d217ddf7524db9c5a7a8923