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Complexes formed in collisions between ultracold alkali-metal diatomic molecules and atoms [dataset] Open Access

We explore the properties of 3-atom complexes of alkali-metal diatomic molecules with alkali-metal atoms, which may be formed in ultracold collisions. We estimate the densities of vibrational states at the energy of atom-diatom collisions, and find values ranging from 2.2 to 350 K^{-1}. However, this density does not account for electronic near-degeneracy or electron and nuclear spins. We consider the fine and hyperfine structure expected for such complexes. The Fermi contact interaction between electron and nuclear spins can cause spin exchange between atomic and molecular spins. It can drive inelastic collisions, with resonances of three distinct types, each with a characteristic width and peak height in the inelastic rate coefficient. Some of these resonances are broad enough to overlap and produce a background loss rate that is approximately proportional to the number of outgoing inelastic channels. Spin exchange can increase the density of states from which laser-induced loss may occur.

Descriptions

Resource type
Dataset
Contributors
Creator: Frye, Matthew D. 1
Hutson, Jeremy M. 1
1 Durham University, UK
Funder
Engineering and Physical Sciences Research Council
Research methods
Other description
Keyword
Ultracold scattering
Sticky collisions
Subject
Ultracold molecules
Location
Language
Cited in
doi:10.1088/1367-2630/ac3ff8
Identifier
ark:/32150/r2sb397829n
doi:10.15128/r2sb397829n
Rights
Creative Commons Attribution 4.0 International (CC BY)

Publisher
Durham University
Date Created

File Details

Depositor
M.D. Frye
Date Uploaded
Date Modified
20 December 2021, 12:12:21
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File format: zip (ZIP Format)
Mime type: application/zip
File size: 1347586
Last modified: 2021:12:19 23:17:39+00:00
Filename: Data_for_repository.zip
Original checksum: 8496e463637c8b2cd40b7f9b12d14466
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User M.D. Frye has updated Complexes formed in collisions between ultracold alkali-metal diatomic molecules and atoms [dataset] over 2 years ago
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User M.D. Frye has updated Supporting data for "Complexes formed in collisions between ultracold alkali-metal diatomic molecules and atoms" over 2 years ago