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Substrate-Independent Epitaxial Growth of the Metal–Organic Framework MOF-508a. [dataset] Open Access

Plasmachemical deposition is a substrate-independent method for the conformal surface functionalization of solid substrates. Structurally well-defined pulsed plasma deposited poly(1-allylimidazole) layers provide surface imidazole linker groups for the directed liquid-phase epitaxial (layer-by-layer) growth of metal–organic frameworks (MOFs) at room temperature. For the case of microporous [Zn (benzene-1,4-dicarboxylate)-(4,4′-bipyridine)0.5] (MOF-508), the MOF-508a polymorph containing two interpenetrating crystal lattice frameworks undergoes orientated Volmer–Weber growth and displays CO2 gas capture behavior at atmospheric concentrations in proportion to the number of epitaxially grown MOF-508 layers.

Descriptions

Resource type
Dataset
Contributors
Creator: Wilson, Matthew 1
1 Durham University, UK
Funder
Engineering and Physical Sciences Research Council
Research methods
Other description
Keyword
CO2 capture
Epitaxial growth
Metal-organic framework (MOF)
MOF coatings
Plasmachemical deposition
Surface functionalization
Subject
Epitaxy
Organometallic chemistry
Surface chemistry
Location
Language
Cited in
doi:10.15128/r25425k9703
Identifier
ark:/32150/r25425k9703
Rights
Creative Commons Attribution 4.0 International (CC BY)

Publisher
Durham University
Date Created

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J.P.S. Badyal
Date Uploaded
Date Modified
12 March 2018, 13:03:44
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File size: 6999334
Last modified: 2018:02:27 17:55:48+00:00
Filename: 180129_Data_Archive.zip
Original checksum: 097a5976bbb25afb42fc3968f1e967e8
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