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Substrate-Independent Epitaxial Growth of the Metal–Organic Framework MOF-508a. [dataset] Open Access

Plasmachemical deposition is a substrate-independent method for the conformal surface functionalization of solid substrates. Structurally well-defined pulsed plasma deposited poly(1-allylimidazole) layers provide surface imidazole linker groups for the directed liquid-phase epitaxial (layer-by-layer) growth of metal–organic frameworks (MOFs) at room temperature. For the case of microporous [Zn (benzene-1,4-dicarboxylate)-(4,4′-bipyridine)0.5] (MOF-508), the MOF-508a polymorph containing two interpenetrating crystal lattice frameworks undergoes orientated Volmer–Weber growth and displays CO2 gas capture behavior at atmospheric concentrations in proportion to the number of epitaxially grown MOF-508 layers.

Descriptions

Resource type

Dataset

Contributors

Creator: Wilson, Matthew ¹

¹ Durham University, UK

Funder

Engineering and Physical Sciences Research Council

Research methods

Other description

Keyword

CO2 capture
Epitaxial growth
Metal-organic framework (MOF)
MOF coatings
Plasmachemical deposition
Surface functionalization

Subject

Epitaxy
Organometallic chemistry
Surface chemistry

Location

Language

Cited in

doi:10.15128/r25425k9703

Identifier

ark:/32150/r25425k9703
doi:10.15128/r25425k9703

Rights

Creative Commons Attribution 4.0 International (CC BY)

Publisher

Durham University

Date Created

File Details

Depositor

J.P.S. Badyal

Date Uploaded

27 February 2018, 17:02:35

Date Modified

1 March 2019, 11:03:04

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Characterization

File format: zip (ZIP Format)

Mime type: application/zip

File size: 6999334

Last modified: 2018:02:27 17:55:48+00:00

Filename: 180129_Data_Archive.zip

Original checksum: 097a5976bbb25afb42fc3968f1e967e8