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Palladium-Poly(Ionic Liquid) Membranes for Permselective Sonochemical Flow Catalysis [dataset] Open Access

Anisotropic palladium–poly(ionic liquid) catalyst membranes have been prepared by complexation of palladium(II) chloride to poly(ionic liquid) functionalised flexible porous substrates. The practical viability of these low loading (sub 0.1 mol%) palladium catalyst membranes for continuous flow reactions at ambient temperature is demonstrated for the Suzuki–Miyaura carbon–carbon coupling reaction by contacting the reactant mixture with the catalyst membrane and applying sonication. The Suzuki–Miyaura carbon–carbon coupling reaction proceeds at the palladium–poly(ionic liquid) catalyst membrane surface in conjunction with selective permeation (separation) of the desired product species through the underlying porous support. These palladium–poly(ionic liquid) catalyst membranes display minimal metal leaching enabling them to be reused multiple times.

Descriptions

Resource type

Dataset

Contributors

Contact person: Badyal, Jas Pal ¹
Creator: Wilson, Matthew ¹

¹ Durham University, UK

Funder

Engineering and Physical Sciences Research Council (EPSRC)

Research methods

Other description

Keyword

Membrane-catalaysis

Subject

Location

Language

Cited in

https://doi.org/10.1016/j.colsurfa.2018.02.044

Identifier

ark:/32150/r1fq977t80v

Rights

All rights reserved All rights reserved

Publisher

Durham University

Date Created

File Details

Depositor

J.P.S. Badyal

Date Uploaded

28 February 2019, 12:02:31

Date Modified

1 March 2019, 11:03:48

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Audits have not yet been run on this file.

Characterization

File format: zip (ZIP Format)

Mime type: application/zip

File size: 8761533

Last modified: 2019:02:28 12:31:50+00:00

Filename: 180314_Catalyst_Membrane.zip

Original checksum: 5024367a6e2b3c4040b0ea25d3152d1a