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Fluorous ‘Ponytails’ Lead to Strong Gelators Showing Thermally Induced Structure Evolution [dataset] Open Access

Abstract from paper: Appending perfluoroalkyl substituents to bis(urea) gelators results in significantly decreased inter-chain interactions with markedly thinner fibres and hence more cross-linked and more transparent gels with potential applications in the crystallisation of fluorinated pharmaceuticals. Gel structure has been probed by detailed SANS measurements which indicate a surprising structure evolution on thermal cycling, not seen for hydrocarbon analogues. The SANS data are complemented by the single crystal X-ray structure of one fluorinated gelator.

Descriptions

Resource type
Dataset
Contributors
Creator: Kumasi, Harshita 1
Creator: Armitage, Sarah E 2
Creator: Kline, Steven R. 3
Creator: Damodaran, Krishna K. 4
Creator: Kennedy, Stuart R. 2
Creator: Atwood, Jerry L. 5
Creator: Steed, Jonathan W. 6
Contact person: Steed, Jonathan W. 6
1 James L. Winkle College of Pharmacy, University of Cincinnati, 3225 Eden Avenue, Cincinnati, USA
2 Department of Chemistry, Durham University, South Road, Durham DH1 3LE, UK
3 NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, USA
4 Department of Chemistry, Science Institute, University of Iceland, Dunhagi 3, 107 Reykjavík, Iceland
5 Department of Chemistry, University of Missouri – Columbia, 601 South College Avenue, Columbia, USA
6 Durham University, UK
Funder
Engineering and Physical Sciences Research Council
Research methods
Other description
Keyword
gel
supramolecular
Subject
Colloids
Location
Language
Cited in
doi:10.1039/C5SM01865J
Identifier
ark:/32150/73666481z
doi:10.15128/73666481z
Rights
Creative Commons Attribution 4.0 International (CC BY)

Publisher
Durham University
Date Created
2015-06-29T00:00:00.000+00:00

File Details

Depositor
S. Palucha
Date Uploaded
Date Modified
17 July 2026, 13:07:37
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User Activity Date
User N. Syrotiuk has updated Fluorous ‘Ponytails’ Lead to Strong Gelators Showing Thermally Induced Structure Evolution [dataset] 10 days ago
User S. Palucha has updated This is holding tile for requested 10.15128/73666481z over 10 years ago
User S. Palucha has updated This is holding tile for requested 10.15128/73666481z over 10 years ago